Letter from Hugh S. Taylor, Princeton University to Michael Heidelberger
Description:
Heidelberger had helped to synthesize cyclooctatetraene, the next higher analog of benzene (consisting of a ring with eight carbon atoms and four double bonds) during a year of postdoctoral study (1911-12) in the laboratory of the 1915 Nobel Laureate, Richard Willstatter, at the Federal Polytechnic Institute in Zurich, Switzerland. His research with Willstatter on cyclooctatetraene was controversial, and was questioned as late as the 1940s by Hugh S. Taylor and Charles D. Hurd. Heidelberger, however, strongly defended his results, pointing out that Taylor and Hurd showed that while cyclooctatetraene resinifies and degrades at high temperatures, he had worked in cold temperatures continuously for 24 hours to synthesize a colorless liquid that was both stable and reactive. Heidelberger and Willstatter's results stood, and as a consequence of their work cyclooctatetraene became a widely used intermediate in organic chemistry.
Number of Image Pages:
2 (106,320 Bytes)
Date:
1939-11-04 (November 4, 1939)
Creator:
Taylor, Hugh S.
Princeton University
Recipient:
Heidelberger, Michael
Rights:
Reproduced with permission of Elizabeth C. Healy.
Subject:
Medical Subject Headings (MeSH):
Chemistry, Organic
Exhibit Category:
The Making of an Immunologist: Heidelberger's Years at the Rockefeller Institute, 1912-1927
Relation:
Letter from Michael Heidelberger to Hugh S. Taylor, Princeton University (September 9, 1939)
Letter from Michael Heidelberger to Hugh S. Taylor, Princeton University (November 7, 1939)
Letter from Michael Heidelberger to Charles D. Hurd, Northwestern University (November 8, 1939)
Letter from Charles D. Hurd, Northwestern University to Michael Heidelberger (November 29, 1939)
Letter from Richard Willstatter to Michael Heidelberger (March 27, 1940)